Transition element–rare earth compounds with Cu5Ca structure

Ternary Rare Earth Transition Metal Zinc Compounds

Forty eight new com pounds RT2Z n2o were prepared by annealing cold-pressed pellets o f the elem ental com ponents in an argon atm osphere. They crystallize with the cubic CeCr^Abo type structure (Fd3m , Z = 8), which was refined from single-crystal diffractom eter data o f TbFeiZn^o (a = 1411.1(1) pm), Y Ru2Z n2o (a = 1422.6(1) pm), D yRu2Z n2o (a = 1422.1(1) pm), G dC o2Z n2o (a = 1406.0(1) p...

Theoretical study of the magnetic ordering in rare-earth compounds with face-centered-cubic structure

Magnetoresistance, specific heat and magnetocaloric effect of equiatomic rare-earth transition-metal magnesium compounds

We present a study of the magnetoresistance, the specific heat and the magnetocaloric effect of equiatomic RETMg intermetallics with RE = La, Eu, Gd, Yb and T = Ag, Au and of GdAuIn. Depending on the composition these compounds are paramagnetic (RE = La, Yb) or they order either ferroor antiferromagnetically with transition temperatures ranging from about 13 to 81K. All of them are metallic, bu...

4f-3d interaction and magnetic anisotropy in ThMn12-type rare-earth transition-metal compounds

Rare-earth (R) transition-metal (T) compounds of the R(T,M)12-type with R = Y or one of the heavy-rare-earth elements, T = Fe or Co and M = Ti, V, Mo or Si, have been studied at 4.2 K in the Amsterdam High-Field Installation in magnetic fields up to 38 T and at temperatures between 4.2 and 1000 K in other magnetometers. The 4f -3d interaction is derived from magnetization measurements on single...

Dielectric constants of binary rare-earth compounds

The dielectric constants of rare-earth oxides (RE2O3) and rare-earth nitrides, phosphides, arsenides, and antimonides (REX, RE = rare-earth element, X = N, P, As, Sb) are quantitatively estimated. The estimation is based on the approximately linear relationship between the dielectric constant and the atomic number of the constituent atoms. Similar correlations are valid in nearly all series of ...